湖南大义山晚侏罗世富硼型成锡矿A型花岗岩成因及地质意义     

孙海瑞  吕志成  韩志锐  杜泽忠  张晓梅  王虎 《岩石学报》2021,37(6):1749-1764

位于南岭成矿带和钦-杭成矿带(简称钦-杭带)交汇部位的湖南大义山锡矿是南岭地区典型的富硼型锡多金属矿床。为厘清大义山锡矿成矿动力学背景,深化南岭地区钨锡矿成矿机制,本文以大义山成锡矿黑云母二长花岗岩为研究对象,开展了系统的岩石学和地球化学研究。研究发现,大义山锡矿具有富硼的特征,成矿黑云母二长花岗岩发育电气石"囊包",电气石在蚀变矿物中广泛发育,并与锡矿化紧密共生,这些特征表明成矿花岗岩具有富硼的特征,并发生了岩浆热液流体出溶。地球化学分析显示,黑云母二长花岗岩具有较高含量的Al_2O_3 (13.67%～14.00%)、Na_20(3.65%～3.90%)、K_2O(3.49%～4.24%)以及较高的FeO~T/(FeOT+MgO)比值(0.95～0.97)、FeO~T/MgO 比值(18.75～32.69)、A/CNK 比值(1.15～1.26)和 10000 × Ga/Al 比值(3.48～4.08),较低的CaO(0.54%～0.59%)、P_2O_5(0.04%～0.06%)含量和锆饱和温度(716～725℃)。球粒陨石标准化稀土元素配分具有明显的四分组效应,强烈的Eu负异常,微量元素富集Rb、Th、U、Ta和Nd等元素,亏损Ba、Nb、Sr、Eu等元素。表明成矿花岗岩具有高分异的特征,与A2型花岗岩特征相近。Nd-Hf同位素分析显示,黑云母二长花岗岩与南岭地区成锡矿花岗岩及钦-杭带A型花岗岩同位素特征基本一致,表明岩浆主要来源于中元古代壳源物质熔融,并有幔源物质的加入。综合本文及前人研究成果,推测南岭地区燕山期伸展作用与Izanagi俯冲板块开天窗或撕裂有关,在此背景下,软流圈物质上涌,引发下地壳物质熔融,形成了富硼的壳幔源混合型花岗质岩浆。岩浆中较高的硼含量促使岩浆发生强烈的结晶分异,并有利于晚期锡矿的形成。  相似文献   

东昆仑祁漫塔格地区乌兰乌珠尔早古生代花岗岩锆石U-Pb年代学、地球化学及其地质意义          下载免费PDF全文

韩志辉  孙丰月  田楠  高宏昶  李良  赵拓飞 《地球科学》2021,46(1):13-30

为确定东昆仑祁漫塔格乌兰乌珠尔地区片麻状黑云母花岗岩和二长花岗岩的形成时代、岩石成因、源区性质和构造背景,对该岩石样品进行了锆石U-Pb年代学、地球化学和锆石Hf同位素研究.结果显示:片麻状黑云母花岗岩加权平均年龄为457.5±2.3 Ma,铝饱和指数A/CNK介于0.98~1.02,属准铝质岩石,Na₂O/K₂O比值为0.440~0.625,属于高钾钙碱性系列.二长花岗岩加权平均年龄为422.5±1.6 Ma,铝饱和指数A/CNK介于1.03~1.05,属弱过铝质岩石.二者均具有高硅(SiO₂介于68.93%~74.72%)、高碱(全碱ALK介于6.83%~9.40%)、低磷(P₂O₅小于0.12%)等特征.富集轻稀土元素,亏损重稀土元素,δEu值为0.29~0.70,显示Eu中度负异常.富集Rb、K等大离子亲石元素,亏损Nb、Ta、P、Ti等高场强元素,属于I型花岗岩.二长花岗岩样品的ε_Hf(t)值为-2.2~+1.4,二阶段模式年龄为1 320~1 546 Ma.结合岩石成岩年龄、地球化学特征及区域构造演化认为片麻状黑云母花岗岩(457.5±2.3 Ma)为下地壳部分熔融产物,形成于原特提斯洋向北俯冲导致的局部拉张环境.二长花岗岩(422.5±1.6 Ma)岩浆来源于中元古代新增生的下部地壳熔融产物,形成于碰撞拼贴后的伸展构造环境.   相似文献   

广西大瑶山东南缘侏罗纪埃达克质花岗岩的特征、成因及构造意义     

许华  韩淑朋  钟锋运  黄启明  白晓  陈子龙 《岩石矿物学杂志》2021,40(6):1074-1092

对钦杭结合带西南段大瑶山东南缘的中晚侏罗世埃达克质花岗岩（165~153 Ma）进行了岩石学、地球化学研究,并探讨了埃达克质和TTG岩类的特征属性。岩石SiO₂含量63.76%~72.13%,总体具高Al₂O₃（Al₂O₃≥15%）、低MgO （<3%）,亏损重稀土元素（HREE）、正Eu异常或弱的负Eu异常,低Y （≤18×10^-6）和Yb （≤1.9×10^-6）,高Sr （>300×10^-6）和Sr/Y值（>20）等埃达克岩独特的地球化学特征。结合区域构造演化分析认为,该侏罗纪埃达克质花岗岩形成于陆内伸展构造背景,为大陆板内加厚（隆起区）的下地壳底部岩石部分熔融的产物,属大陆板内环境I型花岗岩。具有类似于低镁安山岩/闪长岩系列（LMA）和镁安山岩/闪长岩系列（MA）两种高压型TTG亚类的属性,为古俯冲增生带下地壳弧型岩石熔融的继承性特征,与中生代古太平洋俯冲板片熔融过程无关,属非俯冲成因的埃达克/TTG岩类。其空间上与大瑶山东南缘早古生代俯冲增生带高度重合,且与早古生代TTG侵入岩组合紧密相邻,提示它们可能源自于早古生代洋壳俯冲带或大陆边缘弧下地壳玄武质岩石的部分熔融,因而具有洋俯冲成因的特征属性。  相似文献   

西藏甲玛矿床南坑高分异Ⅰ型花岗斑岩及黑云母矿物学特征     

陈国良  张忠坤  孙渺  林彬  赫健  唐攀  格桑顿珠  苏贵喆  任绍渊  胡海涛 《矿物岩石地球化学通报》2021,40(2):411-424

高硅花岗岩对于理解浅部岩浆房的行为具有重要意义。本文对西藏甲玛矿区南坑矿段的花岗斑岩开展了岩相学、岩石地球化学及黑云母矿物学研究。结果显示,该花岗斑岩具有高SiO2(73.39%~77.99%)、高K2O(4.34%~6.45%)和低P2O5(0.03%~0.06%)特征,铝饱和指数为0.97~0.98,富集Rb、Th、U和Pb,明显亏损Ba、Nb、Ta、Sr、P、Ti和Eu等,属准铝质高分异I型花岗岩类;其中的黑云母具有高Al2O3(9.87%~10.92%)、高MgO(13.38%~14.64%)、高F(0.56%~1.11%)和高Cl(0.07%~0.12%)特征,Mg#为0.61~0.63,属镁质黑云母,黑云母源区为壳幔混合源。研究认为,该区花岗斑岩可能为甲玛矿区浅部埃达克质二长花岗斑岩的岩浆经矿物结晶分异演化出高硅残余熔体,并以岩脉形式上侵就位,而残留在岩浆房的物质结晶形成似斑状二长花岗岩,二者构成互补的关系,即主体为似斑状二长花岗岩,补体为高分异花岗斑岩。  相似文献   

东昆仑造山带低山头花岗岩体岩石地球化学特征及其地质意义     

邓红宾  李培龙  魏华财  何文劲  杨鹏涛  李宁  唐华 《吉林大学学报(地球科学版)》2021,51(3):767-782

低山头一带花岗岩体归属东昆仑弧盆系北昆仑岩浆弧带,位于东昆仑成矿带伯喀里克—香日德成矿亚带东昆仑造山带中段,岩石类型主要为石英闪长岩、正长花岗岩及二长花岗岩。为了加强该地区花岗岩体岩石地球化学与成岩成矿背景探讨,对花岗岩体开展了主量元素、微量元素及矿质元素研究。主量元素组成上,石英闪长岩具中硅（57.64%和58.47%）、富钠（Na₂O/K₂O均为2.57）特点,正长花岗岩具高硅（75.45%~75.99%）、富钾（Na₂O/K₂O为0.74~0.94）特点,二长花岗岩具高硅（66.80%~73.45%）、富钠（Na₂O/K₂O为1.50~2.13）特点;花岗岩体铝饱和指数A/CNK<1,为准铝质岩浆岩;碱饱和指数NK/A集中在0.26~0.69之间,属钙碱性岩石;里特曼组合指数σ₄₃在1.18~2.31之间,属钙碱性类型。花岗岩体轻稀土元素相对重稀土元素富集,岩浆分异特征明显,大离子亲石元素（LILE）富集Rb、K、Ba、Th、Sr、Nd,仅正长花岗岩Sr亏损,高场强元素（HFSE）富集Zr、Hf、Ce,而Nb、P、Ti明显亏损,源区物质为壳幔混合物质,属挤压应力环境中同碰撞I型花岗岩。在岩体实测剖面中获得11种元素分析数据,与青海全省、东昆仑成矿带及其亚成矿带平均元素丰度值进行对比,初步划分不同岩性、不同类型、不同时代花岗岩,以及富集的含矿元素为Au、Zn、Y、Pb等。与区域有成矿事实且为I型花岗岩成因进行对比,认为研究区有较好的找矿前景。  相似文献   

辽东石庙沟岩体岩石地球化学特征、锆石U-Pb年龄、Hf同位素及其地质意义     

王世成  杨仲杰  杨菊  张璟  孙守亮  刘长纯 《吉林大学学报(地球科学版)》2021,51(2):429-441

辽东石庙沟地区位于华北陆块东部的辽吉造山/活动带上,该带经历了十分复杂的构造演化过程,记录了多期岩浆-构造-变质事件。石庙沟岩体为花岗斑岩,富SiO₂、Na₂O和K₂O,贫CaO、MgO及Al₂O₃,亏损高场强元素（Nb、Ti、Ta、P）,富集大离子亲石元素（K、Rb、Ba、U）,A/CNK值大于1,REE配分曲线呈"海鸥"式分布,以具有显著的负Eu异常为特征,高Ga/Al值,与典型A型花岗岩特征一致。花岗斑岩中锆石的LA-ICP-MS U-Pb测年结果表明其成岩年龄为（123.0±1.6）Ma,为早白垩世。锆石Hf同位素分析表明,ε_Hf（t）值均为负值,介于-15.72~-12.85之间,平均值为-14.14,二阶段模式年龄（T_DM2）在2 164~1 989 Ma之间,平均为2 067 Ma,反映源岩以大陆壳成分为主。结合花岗斑岩高SiO₂,低Mg、Co、Cr、Ni,且富集LREE和LILE,亏损HFSE等特征,表明早白垩世花岗斑岩岩浆应为大陆地壳物质熔融的产物。根据年代学和岩石地球化学研究认为,早白垩世花岗斑岩是古太平洋板块向欧亚大陆板块俯冲所形成的活动大陆边缘弧花岗岩。研究区早白垩世花岗斑岩的形成主要受太平洋构造域的影响,形成环境受板块俯冲造山后伸展作用和下地壳拆沉作用的联合制约,是辽东地区岩石圈减薄的直接证据。  相似文献   

The role of hydrothermal fluids in sedimentation in saline alkaline lakes: Evidence from Nasikie Engida,Kenya Rift Valley     

Robin W. Renaut  R. Bernhart Owen  Tim K. Lowenstein  Gijs De Cort  Emma Mcnulty  Jennifer J. Scott  Anthony Mbuthia 《Sedimentology》2021,68(1):108-134

Saline alkaline lakes that precipitate sodium carbonate evaporites are most common in volcanic terrains in semi‐arid environments. Processes that lead to trona precipitation are poorly understood compared to those in sulphate‐dominated and chloride‐dominated lake brines. Nasikie Engida (Little Magadi) in the southern Kenya Rift shows the initial stages of soda evaporite formation. This small shallow (<2 m deep; 7 km long) lake is recharged by alkaline hot springs and seasonal runoff but unlike neighbouring Lake Magadi is perennial. This study aims to understand modern sedimentary and geochemical processes in Nasikie Engida and to assess the importance of geothermal fluids in evaporite formation. Perennial hot‐spring inflow waters along the northern shoreline evaporate and become saturated with respect to nahcolite and trona, which precipitate in the southern part of the lake, up to 6 km from the hot springs. Nahcolite (NaHCO₃) forms bladed crystals that nucleate on the lake floor. Trona (Na₂CO₃·NaHCO₃·2H₂O) precipitates from more concentrated brines as rafts and as bottom‐nucleated shrubs of acicular crystals that coalesce laterally to form bedded trona. Many processes modify the fluid composition as it evolves. Silica is removed as gels and by early diagenetic reactions and diatoms. Sulphate is depleted by bacterial reduction. Potassium and chloride, of moderate concentration, remain conservative in the brine. Clastic sedimentation is relatively minor because of the predominant hydrothermal inflow. Nahcolite precipitates when and where pCO₂ is high, notably near sublacustrine spring discharge. Results from Nasikie Engida show that hot spring discharge has maintained the lake for at least 2 kyr, and that the evaporite formation is strongly influenced by local discharge of carbon dioxide. Brine evolution and evaporite deposition at Nasikie Engida help to explain conditions under which ancient sodium carbonate evaporites formed, including those in other East African rift basins, the Eocene Green River Formation (western USA), and elsewhere.  相似文献   

Archean (about 2500 Ma) anatexis in eastern North China Block     

《China Geology》2021,4(2):215-229

Two Neoarchean alkaline feldspar-rich granites sourced from partially melted granulite-facies granodioritic orthogneiss have been here recognised in the eastern part of the North China Block (NCB). These poorly foliated granites have previously been assumed to be Mesozoic in age and never dated, and so their significance has not been recognised until now. The first granite (AG1) is a porphyritic syenogranite with megacrystic K-feldspar, and the second (AG2) is a quartz syenite with perthitic megacryst. Zircons from the granites yield LA-ICP-MS U-Pb ages of 2499 ± 10 Ma (AG1), and 2492 ± 28 Ma (AG2), which are slightly younger than the granodioritic orthogneiss that they intrude with a crystallisation U-Pb age of 2537 ± 34 Ma. The younger granites have higher assays for SiO₂ (71.91% for AG1 and 73.22% for AG2) and K₂O (7.52% for AG1 and 8.37% for AG2), and much lower assays for their other major element than the granodioritic orthogneiss. All of the granodioritic orthogneiss and granite samples have similar trace element patterns, with depletion in Th, U, Nb, and Ti and enrichment in Rb, Ba, K, La, Ce, and P. This indicates that the granites are derived from the orthogneiss as partial melts. Although they exhibit a similar REE pattern, the granites have much lower total REE contents (30.97×10⁻⁶ for AG1, and 25.93×10⁻⁶ for AG2), but pronounced positive Eu anomalies (Eu/Eu* = 8.57 for AG1 and 27.04 for AG2). The granodioritic orthogneiss has an initial ⁸⁷Sr/⁸⁶Sr ratio of 0.70144, εNd(t) value of 3.5, and εHf(t) values ranging from −3.2 to +2.9. The orthogneiss is a product of fractional crystallisation from a dioritic magma, which was derived from a mantle source contaminated by melts derived from a felsic slab. By contrast, the AG1 sample has an initial ⁸⁷Sr/⁸⁶Sr ratio of 0.6926 that is considered too low in value, εNd(t) value of 0.3, and εHf(t) values between +0.57 and +3.82; whereas the AG2 sample has an initial ⁸⁷Sr/⁸⁶Sr ratio of 0.70152, εNd(t) value of 1.3, and εHf(t) values between +0.5 and +14.08. These assays indicate that a Sr-Nd-Hf isotopic disequilibrium exists between the granite and granodioritic orthogneiss. The elevated εHf(t) values of the granites can be explained by the involvement of Hf-bearing minerals, such as orthopyroxene, amphibole, and biotite, in anatectic reactions in the granodioritic orthogneiss. Based on the transitional relationship between the granites and granodioritic orthogneiss and the geochemical characteristics mentioned above, it is concluded that the granites are the product of rapid partial-melting of the granodioritic orthogneiss after granulite-facies metamorphism, and their crystallisation age of about 2500 Ma provides the minimum age of the metamorphism. This about 2500 Ma tectonic-metamorphic event in NCB is similar to the other cratons in India, Antarctica, northern and southern Australia, indicating a possible connection between these cratons during the Neoarchean.  相似文献   

青海省那陵郭勒河中游晚三叠世侵入岩地球化学特征及地质意义     

吉明甲  魏丽琼  徐博  刘博  白洪溪  陈晓琳  李兄 《西北地质》2021,(1)

那陵郭勒河中游位于东昆仑西段祁漫塔格地区,分布着大量的花岗岩。对该地区晚三叠世侵入岩的研究有助于认识东昆仑造山带印支期构造-岩浆演化历史。对研究区内花岗岩进行了岩石学、年代学及岩石地球化学分析。分析结果表明,研究区花岗闪长岩和二长花岗斑岩锆石LA-ICP-MS U-Pb年龄分别为(225.7±1)Ma、(213.74±1)Ma,为晚三叠世岩浆活动产物。岩石地球化学分析结果显示,该地区晚三叠世侵入岩属高钾钙碱性系列,饱和铝指数显示为偏铝质到过铝质,富集Rb、Th、K等大离子亲石元素和轻稀土元素,明显亏损Nb、P、Ti等高场强元素。花岗岩具有I型花岗岩特征,具有板块俯冲阶段的特征。通过分析认为岩浆岩形成于板块碰撞前的火山弧环境中。  相似文献   

海南岛抱伦金矿床双峰式侵入杂岩地球化学特征及对金成矿作用的启示     

林弟  宛胜  胡在龙  吕常艳  单强  梁晓  魏昌欣  袁勤敏  高鹏 《矿床地质》2023,42(6):1229-1246

位于海南岛西南部的抱伦金矿产于尖峰岩体外接触带,与辉绿岩脉密切伴生,这些侵入岩蕴含了金矿成矿作用与岩浆活动-构造演化-成矿体系关系的重要信息。文章报道了对抱伦尖峰花岗岩和辉绿岩开展岩石学、锆石U-Pb年代学、元素和Sm-Nd同位素地球化学研究的成果。本次工作获得了尖峰花岗岩的LA-ICP-MS方法锆石U-Pb年龄为(234.9±2.8)Ma,与辉绿岩构成双峰式侵入杂岩组合。辉绿岩属亚碱性玄武岩系列,相对富集Th、Nb、Ta等强不相容元素,无Nb、Ta、Ti亏损,显示与富集洋中脊玄武岩(E-MORB)相似的地球化学特征,其ε_Nd(t)值为4.11,指示了亏损的源区性质;尖峰花岗岩属高钾钙碱性岩系的铝质A型花岗岩,相对富集K、Rb、Th、Ce等元素,相对亏损Sr、Ba、Nb、Ta、P、Ti等元素,其ε_Nd(t)值为-7.61～-7.80,指示了再循环地壳源区。抱伦辉绿岩为交代型地幔降压熔融的产物,而尖峰花岗岩起源于中元古界泥质和杂砂岩地壳源岩于低压、高温环境下的部分熔融,该双峰式侵入杂岩与金成矿作用形成于造山后伸展-减薄构造背景。双峰式侵入杂岩的...  相似文献